Detail publikačního výsledku

Macromonomers of Polyethylene

HERMANOVÁ, S.; CIHLÁŘ, J.; KUČERA, M.; MERNA, J.

Originální název

Macromonomers of Polyethylene

Anglický název

Macromonomers of Polyethylene

Druh

Stať ve sborníku v databázi WoS či Scopus

Originální abstrakt

Living polymers have a great potential for synthesis new polymer architectures displaying unique properties such as block copolymers and macromonomers. Macromonomers are macromolecules with polymerizable entities at one or both chain ends. Our synthetic method for macromonomers was the termination of a living polymer with additives. Since the phenoxy-imine titanium complex activated by methylaluminoxane (MAO) as cocatalyst promotes living polymerisation of ethylene (Fujita et al, 2002), the polymer chain ends remain active after the consumption of monomer. Because of the possibility of end functional group detection in IR and NMR spectra polyethylene oligomers with molar masses about 5 000 g/mol were prepared.Iodine, propylene oxide, styrene, methyl acrylate, 10-undecen-1-ol and 10-undecenoic acid were examined as the additives

Anglický abstrakt

Living polymers have a great potential for synthesis new polymer architectures displaying unique properties such as block copolymers and macromonomers. Macromonomers are macromolecules with polymerizable entities at one or both chain ends. Our synthetic method for macromonomers was the termination of a living polymer with additives. Since the phenoxy-imine titanium complex activated by methylaluminoxane (MAO) as cocatalyst promotes living polymerisation of ethylene (Fujita et al, 2002), the polymer chain ends remain active after the consumption of monomer. Because of the possibility of end functional group detection in IR and NMR spectra polyethylene oligomers with molar masses about 5 000 g/mol were prepared.Iodine, propylene oxide, styrene, methyl acrylate, 10-undecen-1-ol and 10-undecenoic acid were examined as the additives

Klíčová slova

living, titanium, macromonomer

Klíčová slova v angličtině

living, titanium, macromonomer

Autoři

HERMANOVÁ, S.; CIHLÁŘ, J.; KUČERA, M.; MERNA, J.

Vydáno

17.12.2006

Nakladatel

National Chemical Laboratory

Místo

Pune

Kniha

MACRO-2006

Edice

1

Strany od

1

Strany do

5

Strany počet

5

Plný text v Digitální knihovně

http://hdl.handle.net/

BibTex

@inproceedings{BUT24862,
  author="Soňa {Hermanová} and Jaroslav {Cihlář} and Miloslav {Kučera} and Jan {Merna}",
  title="Macromonomers of Polyethylene",
  booktitle="MACRO-2006",
  year="2006",
  series="1",
  number="1",
  pages="1--5",
  publisher="National Chemical Laboratory",
  address="Pune"
}