Detail publikačního výsledku

A differential scanning calorimetry (DSC) approach for assessing the quality of polyethylene terephthalate (PET) waste for physical recycling: a proof-of-concept study

ŠUDOMOVÁ, L.; DOLEŽALOVÁ WEISSMANNOVÁ, STEINMENTZ Z.; H.; ŘEZÁČOVÁ, V.; KUČERÍK, J.

Originální název

A differential scanning calorimetry (DSC) approach for assessing the quality of polyethylene terephthalate (PET) waste for physical recycling: a proof-of-concept study

Anglický název

A differential scanning calorimetry (DSC) approach for assessing the quality of polyethylene terephthalate (PET) waste for physical recycling: a proof-of-concept study

Druh

Článek WoS

Originální abstrakt

Physical recycling of plastics is among the most important approaches of circular economy. The efficiency of the recycling is influenced by many factors including the number of recycling cycles, composition of plastics, chemical modifications, additives and others. Currently, however, there are no methods enabling to distinguish the quality of plastics for recycling. In this work, we address this issue and suggest a new method based on the correlation of solely thermophysical properties of polyethylene terephthalate (PET) waste obtained using differential scanning calorimetry (DSC) during repeated heating and cooling. The combination of results of differential scanning calorimetry and advanced statistical methods enabled to separate 76 PET samples into six groups according to their origin, chemical modification, degradation and suitability for recycling. The discriminant analysis enabled to suggest a model which uses for the discrimination a combination of temperatures and enthalpies of melting and crystallization. The approach illustrates that thermophysical properties, which can be obtained using a single DSC experiment, can be used to distinguish the polymers of various origin and quality.

Anglický abstrakt

Physical recycling of plastics is among the most important approaches of circular economy. The efficiency of the recycling is influenced by many factors including the number of recycling cycles, composition of plastics, chemical modifications, additives and others. Currently, however, there are no methods enabling to distinguish the quality of plastics for recycling. In this work, we address this issue and suggest a new method based on the correlation of solely thermophysical properties of polyethylene terephthalate (PET) waste obtained using differential scanning calorimetry (DSC) during repeated heating and cooling. The combination of results of differential scanning calorimetry and advanced statistical methods enabled to separate 76 PET samples into six groups according to their origin, chemical modification, degradation and suitability for recycling. The discriminant analysis enabled to suggest a model which uses for the discrimination a combination of temperatures and enthalpies of melting and crystallization. The approach illustrates that thermophysical properties, which can be obtained using a single DSC experiment, can be used to distinguish the polymers of various origin and quality.

Klíčová slova

Polyethylene terephthalate; PET; PET-G; DSC; Recycling; Model

Klíčová slova v angličtině

Polyethylene terephthalate; PET; PET-G; DSC; Recycling; Model

Autoři

ŠUDOMOVÁ, L.; DOLEŽALOVÁ WEISSMANNOVÁ, STEINMENTZ Z.; H.; ŘEZÁČOVÁ, V.; KUČERÍK, J.

Rok RIV

2024

Vydáno

08.08.2023

Nakladatel

Springer Nature

Místo

DORDRECHT

ISSN

1588-2926

Periodikum

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY

Svazek

148

Číslo

20

Stát

Maďarsko

Strany od

10843

Strany do

10855

Strany počet

13

URL

https://link.springer.com/article/10.1007/s10973-023-12430-8

Plný text v Digitální knihovně

http://hdl.handle.net/11012/245018

BibTex

@article{BUT184759,
  author="Lucie {Šudomová} and Helena {Doležalová Weissmannová} and Zacharias {Steinmetz} and Veronika {Řezáčová} and Jiří {Kučerík}",
  title="A differential scanning calorimetry (DSC) approach for assessing the quality of polyethylene terephthalate (PET) waste for physical recycling: a proof-of-concept study",
  journal="JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY",
  year="2023",
  volume="148",
  number="20",
  pages="10843--10855",
  doi="10.1007/s10973-023-12430-8",
  issn="1388-6150",
  url="https://link.springer.com/article/10.1007/s10973-023-12430-8"
}

Dokumenty

s10973-023-12430-8