Detail publikace

Co-pyrolysis of lychee and plastic waste as a source of bioenergy through kinetic study and thermodynamic analysis

Zhang, Y., Ahmad, M.S., Shen, B., Yuan, P., Shah, I.A., Zhu, Q., Ibrahim, M., Bokhari, A., Klemeš, J.J., Elkamel, A.

Originální název

Co-pyrolysis of lychee and plastic waste as a source of bioenergy through kinetic study and thermodynamic analysis

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

The use of hazardous materials like plastic waste can be improved by adding value to viable biomass candidates. The current study is focused on lychee and plastic waste co-pyrolysis for the production of energy and chemicals. Based on this knowledge of the subject matter sample mixture was pyrolysed at four different heating rates: 10 °C min−1, 20 °C min−1, 30 °C min−1, and 40 °C min−1. To establish the pyrolysis reaction process, the data was subjected to kinetic modelling, which predicted thermodynamic parameters. The co-pyrolysis standard method of lychee and plastic waste demonstrated 83% of thermal degradation was achieved. This result proves that the co-pyrolysis of lychee waste and waste plastics can increase the output of bio-oil, reduce carbon coking, improve profitability and cost competitiveness, make industrial production possible and environmentally friendly. The kinetic parameters, such as average activation energy, pre-exponential factors, enthalpy and Gibbs free energy, were shown to be 64 kJ mol−1 to 71 kJ mol−1, 102 s−1 to 1011 s−1, 58 kJ mol−1 to 65 kJ mol−1 and 299 kJ mol−1 to 308 kJ mol−1. The obtained quantitative synergetic kinetic and thermodynamic attributes of lychee and plastic waste may indicate its potential for bioenergy generation.

Klíčová slova

Co-pyrolysis; Kinetic modelling; Lychee waste; Plastic waste; Thermodynamics parameters

Autoři

Zhang, Y., Ahmad, M.S., Shen, B., Yuan, P., Shah, I.A., Zhu, Q., Ibrahim, M., Bokhari, A., Klemeš, J.J., Elkamel, A.

Vydáno

1. 10. 2022

Nakladatel

Elsevier Ltd

ISSN

0360-5442

Periodikum

Energy

Číslo

256

Stát

Spojené království Velké Británie a Severního Irska

Strany od

124678

Strany do

124678

Strany počet

8

URL

https://www-sciencedirect-com.ezproxy.lib.vutbr.cz/science/article/pii/S036054422201581X

BibTex

@article{BUT178611,
  author="Syed Awais Ali Shah {Bokhari} and Jiří {Klemeš}",
  title="Co-pyrolysis of lychee and plastic waste as a source of bioenergy through kinetic study and thermodynamic analysis",
  journal="Energy",
  year="2022",
  number="256",
  pages="124678--124678",
  doi="10.1016/j.energy.2022.124678",
  issn="0360-5442",
  url="https://www-sciencedirect-com.ezproxy.lib.vutbr.cz/science/article/pii/S036054422201581X"
}