Detail publikačního výsledku

Lanthanide-Based Metal-Organic-Frameworks for Proton Conduction and Magnetic Properties

BISWAS, S.; NEUGEBAUER, P.

Originální název

Lanthanide-Based Metal-Organic-Frameworks for Proton Conduction and Magnetic Properties

Anglický název

Lanthanide-Based Metal-Organic-Frameworks for Proton Conduction and Magnetic Properties

Druh

Článek WoS

Originální abstrakt

The coexistence of proton conductivity and magnetic properties in metal organic frameworks (MOFs) is simply an attractive prospect to design and create multifunctional molecular materials. However, the simultaneity of interesting magnetic properties (eg. magnetocaloric effect, slow magnetic relaxation or magnetic ordering) and proton conduction in a MOF is very implausible to be observed, as chemical and structural necessities are absolutely poles apart for either of the properties. In this context, lanthanide-based metal-organic frameworks (LMOFs) have emerged as an intriguing class of materials to observe such coexistence in few cases. In this perspective, the advantages of combining lanthanide ions and organic acids as ligands to construct a proton-conductive magnetic metal organic framework are briefly discussed. The current status of this specific research area regarding some fascinating LMOFs exhibiting proton conductivity and magnetic properties is reviewed in detail. Also, a future perspective of such materials is discussed.

Anglický abstrakt

The coexistence of proton conductivity and magnetic properties in metal organic frameworks (MOFs) is simply an attractive prospect to design and create multifunctional molecular materials. However, the simultaneity of interesting magnetic properties (eg. magnetocaloric effect, slow magnetic relaxation or magnetic ordering) and proton conduction in a MOF is very implausible to be observed, as chemical and structural necessities are absolutely poles apart for either of the properties. In this context, lanthanide-based metal-organic frameworks (LMOFs) have emerged as an intriguing class of materials to observe such coexistence in few cases. In this perspective, the advantages of combining lanthanide ions and organic acids as ligands to construct a proton-conductive magnetic metal organic framework are briefly discussed. The current status of this specific research area regarding some fascinating LMOFs exhibiting proton conductivity and magnetic properties is reviewed in detail. Also, a future perspective of such materials is discussed.

Klíčová slova

Lanthanides; Magnetic properties; Magnetic refrigeration; Metal-organic frameworks; Proton conductivity

Klíčová slova v angličtině

Lanthanides; Magnetic properties; Magnetic refrigeration; Metal-organic frameworks; Proton conductivity

Autoři

BISWAS, S.; NEUGEBAUER, P.

Rok RIV

2022

Vydáno

07.12.2021

Nakladatel

Wiley-VCH

Místo

WEINHEIM

ISSN

1099-0682

Periodikum

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Svazek

2021

Číslo

45

Stát

Spolková republika Německo

Strany od

4610

Strany do

4618

Strany počet

9

URL

https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100686

Plný text v Digitální knihovně

http://hdl.handle.net/11012/204010

BibTex

@article{BUT174922,
  author="Soumava {Biswas} and Petr {Neugebauer}",
  title="Lanthanide-Based Metal-Organic-Frameworks for Proton Conduction and Magnetic Properties",
  journal="EUROPEAN JOURNAL OF INORGANIC CHEMISTRY",
  year="2021",
  volume="2021",
  number="45",
  pages="4610--4618",
  doi="10.1002/ejic.202100686",
  issn="1434-1948",
  url="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100686"
}

Dokumenty

Biswas_2021