Přístupnostní navigace
E-přihláška
Vyhledávání Vyhledat Zavřít
Detail publikace
YING, Y. BROWNE, M. PUMERA, M.
Originální název
Metal-organic-frameworks on 3D-printed electrodes:in situelectrochemical transformation towards the oxygen evolution reaction
Typ
článek v časopise ve Web of Science, Jimp
Jazyk
angličtina
Originální abstrakt
Metal-organic framework (MOF) derived materials are important alternatives for electrochemical energy storage and conversion, due to their highly large surface area, abundant active sites, and diversity in composition and structure. In this work, a controllable electrochemical transformation of ZIF-67 into active porous metal oxides is employed for the oxygen evolution reaction (OER). ZIF-67 is directly coated onto the surface of three-dimensional (3D) printed titanium (Ti) electrodes using a step-by-stepin situgrowth and then converted into cobalt oxide (Co3O4) by electrochemical cycling, designated as ZIF-67/Ti-E electrode. Raman spectroscopy, scanning electron microscopy (SEM), and cyclic voltammetry (CV) have been used to verify the electrochemical transformation from octahedral ZIF-67 to thin sheet-shaped Co3O4. This large-surface-area Co3O4, as well as the existence of Co(IV)species right before water oxidation, plays a critical role in enhanced OER performance under alkaline electrolysis conditions. The optimized ZIF-67/Ti-E electrode has demonstrated a better OER performance with a low overpotential of 360 mV at a current density of 10 mA cm(-2)and excellent durability, compared with its counterparts produced by the widely popular calcination method. Our method provides a simplein situ, fast, mild, and energy-efficient approach to employ MOF-derived materials as promising OER catalysts using scaled-up 3D-printed electrodes.
Klíčová slova
CATALYTIC-PROPERTIES; GAS-ADSORPTION; ELECTROCATALYSTS; COBALT; ZIF-67; REDUCTION; MONOLITHS; REMOVAL; CO2
Autoři
YING, Y.; BROWNE, M.; PUMERA, M.
Vydáno
1. 7. 2020
Nakladatel
ROYAL SOC CHEMISTRY
Místo
CAMBRIDGE
ISSN
2398-4902
Periodikum
SUSTAINABLE ENERGY & FUELS
Ročník
4
Číslo
7
Stát
Spojené království Velké Británie a Severního Irska
Strany od
3732
Strany do
3738
Strany počet
URL
https://pubs.rsc.org/en/content/articlelanding/2020/SE/D0SE00503G#!divAbstract
BibTex
@article{BUT167493, author="Yulong {Ying} and Michelle P. {Browne} and Martin {Pumera}", title="Metal-organic-frameworks on 3D-printed electrodes:in situelectrochemical transformation towards the oxygen evolution reaction", journal="SUSTAINABLE ENERGY & FUELS", year="2020", volume="4", number="7", pages="3732--3738", doi="10.1039/d0se00503g", issn="2398-4902", url="https://pubs.rsc.org/en/content/articlelanding/2020/SE/D0SE00503G#!divAbstract" }