Detail publikačního výsledku

Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives

CIGÁNEK, M.; HEINRICHOVÁ, P.; KUČERÍK, J.; KRAJČOVIČ, J.

Originální název

Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives

Anglický název

Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives

Druh

Abstrakt

Originální abstrakt

The series of three DPP derivatives was prepared by nucleophilic substitution of 1-(2-bromoethyl)adamantane chains. The main aim of this work was to focus on isolation of all three possible formed products (NN-; N,O- and O,O-alkylated) and investigate their properties. In this work it was discovered that adamantyl chains has a significant role in the crystallinity of O-alkylated derivative. Furthermore, optical properties were investigated for all prepared derivatives, both in solution and in thin layers. The position of alkyl chains in the DPP molecule significantly affected both absorption and fluorescence emission spectra. The thermal stability of N- and O-alkylated derivatives also differed significantly.

Anglický abstrakt

The series of three DPP derivatives was prepared by nucleophilic substitution of 1-(2-bromoethyl)adamantane chains. The main aim of this work was to focus on isolation of all three possible formed products (NN-; N,O- and O,O-alkylated) and investigate their properties. In this work it was discovered that adamantyl chains has a significant role in the crystallinity of O-alkylated derivative. Furthermore, optical properties were investigated for all prepared derivatives, both in solution and in thin layers. The position of alkyl chains in the DPP molecule significantly affected both absorption and fluorescence emission spectra. The thermal stability of N- and O-alkylated derivatives also differed significantly.

Klíčová slova

diketopyrrolopyrrole; asymmetrical alkylation; adamantyl

Klíčová slova v angličtině

diketopyrrolopyrrole; asymmetrical alkylation; adamantyl

Autoři

CIGÁNEK, M.; HEINRICHOVÁ, P.; KUČERÍK, J.; KRAJČOVIČ, J.

Vydáno

21.11.2019

Nakladatel

Vysoké učení technické v Brně, Fakulta chemická

Místo

Brno

ISBN

978-80-214-5807-9

Kniha

Studentská odborná konference Chemie je život 2019

Edice

první

Strany od

72

Strany do

72

Strany počet

1

BibTex

@misc{BUT160834,
  author="Martin {Cigánek} and Patricie {Heinrichová} and Jiří {Kučerík} and Jozef {Krajčovič}",
  title="Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives",
  booktitle="Studentská odborná konference Chemie je život 2019",
  year="2019",
  series="první",
  pages="72--72",
  publisher="Vysoké učení technické v Brně, Fakulta chemická",
  address="Brno",
  isbn="978-80-214-5807-9",
  note="Abstract"
}