Detail publikačního výsledku

Utilization of fractional extraction for characterization of the interactions between humic acids and metals

KALINA, M.; KLUČÁKOVÁ, M.; SEDLÁČEK, P.

Originální název

Utilization of fractional extraction for characterization of the interactions between humic acids and metals

Anglický název

Utilization of fractional extraction for characterization of the interactions between humic acids and metals

Druh

Článek recenzovaný mimo WoS a Scopus

Originální abstrakt

Diffusion experiments in humic hydrogels provide valuable findings on reactivity of humic matrices. This article concentrates on the study of interactions between humic acids and copper(II) ions in diffusion experiments. The diffusion experiments were supplemented with selective extraction of the diffused copper(II) ions. For this purpose, the leaching agents with increasing affinity towards copper(II) ions were used. The presented results showed that several different forms of the diffused ions exist in the humic gel, which is given by the strength of bonds towards humic acids. Distribution of copper into these forms becomes constant after someinitial period, which indicates local equilibration of interactions between the ions and the humic content of the gel during the transport process. The proposed experimental method seems promising in order to shed newlight on the effects of humic acids reactivity on mobility of important compounds in nature.

Anglický abstrakt

Diffusion experiments in humic hydrogels provide valuable findings on reactivity of humic matrices. This article concentrates on the study of interactions between humic acids and copper(II) ions in diffusion experiments. The diffusion experiments were supplemented with selective extraction of the diffused copper(II) ions. For this purpose, the leaching agents with increasing affinity towards copper(II) ions were used. The presented results showed that several different forms of the diffused ions exist in the humic gel, which is given by the strength of bonds towards humic acids. Distribution of copper into these forms becomes constant after someinitial period, which indicates local equilibration of interactions between the ions and the humic content of the gel during the transport process. The proposed experimental method seems promising in order to shed newlight on the effects of humic acids reactivity on mobility of important compounds in nature.

Klíčová slova

humic acids, hydrogels, diffusion, heavy metal, fractional extraction

Klíčová slova v angličtině

humic acids, hydrogels, diffusion, heavy metal, fractional extraction

Autoři

KALINA, M.; KLUČÁKOVÁ, M.; SEDLÁČEK, P.

Rok RIV

2014

Vydáno

21.04.2013

Nakladatel

Elsevier

Místo

AMSTERDAM, NETHERLANDS

ISSN

0016-7061

Periodikum

Geoderma

Svazek

207-208

Číslo

10

Stát

Nizozemsko

Strany od

92

Strany do

98

Strany počet

7

BibTex

@article{BUT100017,
  author="Michal {Kalina} and Martina {Klučáková} and Petr {Sedláček}",
  title="Utilization of fractional extraction for characterization of the interactions between humic acids and metals",
  journal="Geoderma",
  year="2013",
  volume="207-208",
  number="10",
  pages="92--98",
  doi="10.1016/j.geoderma.2013.04.031",
  issn="0016-7061"
}