Detail publikace

Synthesis and characterization of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group

VYŠVAŘIL, M. DASTYCH, D. TARABA, J. NEČAS, M.

Originální název

Synthesis and characterization of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group

Anglický název

Synthesis and characterization of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group

Jazyk

en

Originální abstrakt

A series of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group were synthesized and characterized by 1H, 13C{1H} and 31P NMR spectroscopy, IR and MS. PhmPCln (m = 3; n, n = 3, 2, 1) reacted with 3,3,4,4-tetramethylsuccinimide (TH) and potassium 3,3,4,4-tetramethylsuccinimidate to give corresponding PhmPTn. Molecular structures of products were established by single-crystal X-ray diffraction experiments. Attempts to prepare new imidophosphoranes by reactions of 1 with PhmPCln (m = 5; n, n = 4, 3, 2) resulted in phosphine oxides. In these reactions the phosphoryl group was formed and we characterized a by-product of this type of reaction.

Anglický abstrakt

A series of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group were synthesized and characterized by 1H, 13C{1H} and 31P NMR spectroscopy, IR and MS. PhmPCln (m = 3; n, n = 3, 2, 1) reacted with 3,3,4,4-tetramethylsuccinimide (TH) and potassium 3,3,4,4-tetramethylsuccinimidate to give corresponding PhmPTn. Molecular structures of products were established by single-crystal X-ray diffraction experiments. Attempts to prepare new imidophosphoranes by reactions of 1 with PhmPCln (m = 5; n, n = 4, 3, 2) resulted in phosphine oxides. In these reactions the phosphoryl group was formed and we characterized a by-product of this type of reaction.

Dokumenty

BibTex 


@article{BUT48955,
  author="Martin {Vyšvařil}",
  title="Synthesis and characterization of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group",
  annote="A series of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group were synthesized and characterized by 1H, 13C{1H} and 31P NMR spectroscopy, IR and MS. 
PhmPCln (m = 3; n, n = 3, 2, 1) reacted with 3,3,4,4-tetramethylsuccinimide (TH) and potassium 3,3,4,4-tetramethylsuccinimidate to give corresponding PhmPTn. 
Molecular structures of products were established by single-crystal X-ray diffraction experiments. Attempts to prepare new imidophosphoranes by reactions of 1 with PhmPCln (m = 5; n, n = 4, 3, 2) 
resulted in phosphine oxides. In these reactions the phosphoryl group was formed and we characterized a by-product of this type of reaction.",
  address="Elsevier",
  chapter="48955",
  institution="Elsevier",
  journal="INORGANICA CHIMICA ACTA",
  number="362",
  volume="2009",
  year="2009",
  month="november",
  pages="4899--4905",
  publisher="Elsevier",
  type="journal article in Web of Science"
}