Detail publikačního výsledku

Improved crystallinity of the novel asymmetrical substituted diketopyrrolopyrrole derivatives (DPPs) by the adamantane side chains

CIGÁNEK, M.; HEINRICHOVÁ, P.; KOVALENKO, A.; VALA, M.; WEITER, M.; KRAJČOVIČ, J.

Originální název

Improved crystallinity of the novel asymmetrical substituted diketopyrrolopyrrole derivatives (DPPs) by the adamantane side chains

Anglický název

Improved crystallinity of the novel asymmetrical substituted diketopyrrolopyrrole derivatives (DPPs) by the adamantane side chains

Druh

Abstrakt

Originální abstrakt

The series of totally six DPP derivatives was prepared. The derivatives were modified by nucleophilic substitution by two alkyl chains - 2-ethylhexyl and adamantyl-ethyl. A typical limitation of this type of reaction is its very poor selectivity, leading to the formation of 3 products - N,N-; N,O- and O,O-alkylated. The synthesis was performed in order to prepare and isolate all three possible products and subsequently explore their properties and find possible utilization. Thermal and optical properties were investigated and the effect of both the alkyl chain character and the binding site in the DPP molecule was evaluated.

Anglický abstrakt

The series of totally six DPP derivatives was prepared. The derivatives were modified by nucleophilic substitution by two alkyl chains - 2-ethylhexyl and adamantyl-ethyl. A typical limitation of this type of reaction is its very poor selectivity, leading to the formation of 3 products - N,N-; N,O- and O,O-alkylated. The synthesis was performed in order to prepare and isolate all three possible products and subsequently explore their properties and find possible utilization. Thermal and optical properties were investigated and the effect of both the alkyl chain character and the binding site in the DPP molecule was evaluated.

Klíčová slova

diketopyrrolopyrrole; alkylation; asymmetrical nucleophilic substitution; adamantyl

Klíčová slova v angličtině

diketopyrrolopyrrole; alkylation; asymmetrical nucleophilic substitution; adamantyl

Autoři

CIGÁNEK, M.; HEINRICHOVÁ, P.; KOVALENKO, A.; VALA, M.; WEITER, M.; KRAJČOVIČ, J.

Vydáno

02.06.2019

Kniha

14th International Symposium on Functional π-Electron Systems (Fπ14) Berlin (June 2 - 7, 2019)

Strany od

39

Strany do

39

Strany počet

1

URL

https://fpi14.hu-berlin.de/wp-content/uploads/2019/06/Book-of-Abstracts-Poster-Presentations.pdf

BibTex

@misc{BUT160791,
  author="Martin {Cigánek} and Patricie {Heinrichová} and Alexander {Kovalenko} and Martin {Vala} and Martin {Weiter} and Jozef {Krajčovič}",
  title="Improved crystallinity of the novel asymmetrical substituted diketopyrrolopyrrole derivatives (DPPs) by the adamantane side chains",
  booktitle="14th International Symposium on Functional π-Electron Systems (Fπ14) Berlin (June 2 - 7, 2019)",
  year="2019",
  pages="39--39",
  url="https://fpi14.hu-berlin.de/wp-content/uploads/2019/06/Book-of-Abstracts-Poster-Presentations.pdf",
  note="Abstract"
}