Detail publikačního výsledku

Novel Riboflavin-Inspired Conjugated Bio-Organic Semiconductors

RICHTÁR, J.; HEINRICHOVÁ, P.; APAYDIN, D.; SCHMIEDOVÁ, V.; YUMUSAK, C.; KOVALENKO, A.; WEITER, M.; SARICIFTCI, N.; KRAJČOVIČ, J.

Originální název

Novel Riboflavin-Inspired Conjugated Bio-Organic Semiconductors

Anglický název

Novel Riboflavin-Inspired Conjugated Bio-Organic Semiconductors

Druh

Článek WoS

Originální abstrakt

Flavins are known to be extremely versatile, thus enabling routes to innumerable modifications in order to obtain desired properties. Thus, in the present paper, the group of bio-inspired conjugated materials based on the alloxazine core is synthetized using two efficient novel synthetic approaches providing relatively high reaction yields. The comprehensive characterization of the materials, in order to evaluate the properties and application potential, has shown that the modification of the initial alloxazine core with aromatic substituents allows fine tuning of the optical bandgap, position of electronic orbitals, absorption and emission properties. Interestingly, the compounds possess multichromophoric behavior, which is assumed to be the results of an intramolecular proton transfer.

Anglický abstrakt

Flavins are known to be extremely versatile, thus enabling routes to innumerable modifications in order to obtain desired properties. Thus, in the present paper, the group of bio-inspired conjugated materials based on the alloxazine core is synthetized using two efficient novel synthetic approaches providing relatively high reaction yields. The comprehensive characterization of the materials, in order to evaluate the properties and application potential, has shown that the modification of the initial alloxazine core with aromatic substituents allows fine tuning of the optical bandgap, position of electronic orbitals, absorption and emission properties. Interestingly, the compounds possess multichromophoric behavior, which is assumed to be the results of an intramolecular proton transfer.

Klíčová slova

bio-inspired material; conjugated materials; flavins; biomimetic energy storage; oxygen evolution

Klíčová slova v angličtině

bio-inspired material; conjugated materials; flavins; biomimetic energy storage; oxygen evolution

Autoři

RICHTÁR, J.; HEINRICHOVÁ, P.; APAYDIN, D.; SCHMIEDOVÁ, V.; YUMUSAK, C.; KOVALENKO, A.; WEITER, M.; SARICIFTCI, N.; KRAJČOVIČ, J.

Rok RIV

2019

Vydáno

05.09.2018

Nakladatel

MDPI

Místo

Switzerland

ISSN

1420-3049

Periodikum

MOLECULES

Svazek

2018

Číslo

23

Stát

Švýcarská konfederace

Strany od

2271

Strany do

2289

Strany počet

18

URL

http://www.mdpi.com/1420-3049/23/9/2271

Plný text v Digitální knihovně

http://hdl.handle.net/11012/137082

BibTex

@article{BUT149690,
  author="Jan {Richtár} and Patricie {Heinrichová} and Dogukan Hazar {Apaydin} and Veronika {Schmiedová} and Cigdem {Yumusak} and Alexander {Kovalenko} and Martin {Weiter} and N.S. {Sariciftci} and Jozef {Krajčovič}",
  title="Novel Riboflavin-Inspired Conjugated Bio-Organic Semiconductors",
  journal="MOLECULES",
  year="2018",
  volume="2018",
  number="23",
  pages="2271--2289",
  doi="10.3390/molecules23092271",
  url="http://www.mdpi.com/1420-3049/23/9/2271"
}