Detail publikačního výsledku

Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity

KOPEL, P.; DOLEŽAL, K.; LANGER, V.; JUN, D.; ADAM, V.; KUČA, K.; KIZEK, R.

Originální název

Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity

Anglický název

Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity

Druh

Článek WoS

Originální abstrakt

The complexes of Fe(II), Mn(II) and Ni(II) with a combination of a Schiff base, nitrogen-donor ligand or macrocyclic ligand and trithiocyanuric acid (ttcH3) were prepared and characterized by elemental analysis and spectroscopies. Crystal and molecular structures of the iron complex of composition [Fe(L1)](ttcH2)(ClO4) EtOH H2O (1), where L1 is Schiff base derived from tris(2-aminoethyl)amine and 2-pyridinecarboxaldehyde, were solved. It was found that the Schiff base is coordinated to the central iron atom by six nitrogens forming deformed octahedral arrangement, whereas trithiocyanurate(1-) anion, perchlorate and solvent molecules are not coordinated. The X-ray structure of the Schiff base sodium salt is also presented and compared with the iron complex. The anticholinesterase activity of the complexes was also studied.

Anglický abstrakt

The complexes of Fe(II), Mn(II) and Ni(II) with a combination of a Schiff base, nitrogen-donor ligand or macrocyclic ligand and trithiocyanuric acid (ttcH3) were prepared and characterized by elemental analysis and spectroscopies. Crystal and molecular structures of the iron complex of composition [Fe(L1)](ttcH2)(ClO4) EtOH H2O (1), where L1 is Schiff base derived from tris(2-aminoethyl)amine and 2-pyridinecarboxaldehyde, were solved. It was found that the Schiff base is coordinated to the central iron atom by six nitrogens forming deformed octahedral arrangement, whereas trithiocyanurate(1-) anion, perchlorate and solvent molecules are not coordinated. The X-ray structure of the Schiff base sodium salt is also presented and compared with the iron complex. The anticholinesterase activity of the complexes was also studied.

Klíčová slova

trithiocyanuric acid; trimercaptotriazine; crystal structure; complexes; acetylcholinesterase activity; Schiff base

Klíčová slova v angličtině

trithiocyanuric acid; trimercaptotriazine; crystal structure; complexes; acetylcholinesterase activity; Schiff base

Autoři

KOPEL, P.; DOLEŽAL, K.; LANGER, V.; JUN, D.; ADAM, V.; KUČA, K.; KIZEK, R.

Rok RIV

2017

Vydáno

08.04.2014

Nakladatel

MDPI

ISSN

1420-3049

Periodikum

MOLECULES

Svazek

19

Číslo

4

Stát

Švýcarská konfederace

Strany od

4338

Strany do

4354

Strany počet

17

URL

http://www.mdpi.com/1420-3049/19/4/4338

Plný text v Digitální knihovně

http://hdl.handle.net/11012/63717

BibTex

@article{BUT109374,
  author="Pavel {Kopel} and Karel {Doležal} and Vratislav {Langer} and Daniel {Jun} and Vojtěch {Adam} and Kamil {Kuča} and René {Kizek}",
  title="Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity",
  journal="MOLECULES",
  year="2014",
  volume="19",
  number="4",
  pages="4338--4354",
  doi="10.3390/molecules19044338",
  url="http://www.mdpi.com/1420-3049/19/4/4338"
}

Dokumenty

molecules-19-04338-v2