Interface-Induced Room-Temperature Ferromagnetism in Hydrogenated Epitaxial Graphene

Interface-Induced Room-Temperature Ferromagnetism in Hydrogenated Epitaxial Graphene

Článek recenzovaný mimo WoS a Scopus

We show ferromagnetic properties of hydrogen-functionalized epitaxial graphene on SiC. Ferromagnetism in such a material is not directly evident as it is inherently composed of only nonmagnetic constituents. Our results nevertheless show strong ferromagnetism with a saturation of 0:9mí B=hexagon projected area, which cannot be explained by simple magnetic impurities. The ferromagnetism is unique to hydrogenated epitaxial graphene on SiC, where interactions with the interfacial buffer layer play a crucial role. We argue that the origin of the observed ferromagnetism is governed by electron correlation effects of the narrow Si dangling bond states in the buffer layer exchange coupled to localized states in the hydrogenated graphene layer. This forms a quasi-three-dimensional ferromagnet with a Curie temperature higher than 300 K.

We show ferromagnetic properties of hydrogen-functionalized epitaxial graphene on SiC. Ferromagnetism in such a material is not directly evident as it is inherently composed of only nonmagnetic constituents. Our results nevertheless show strong ferromagnetism with a saturation of 0:9mí B=hexagon projected area, which cannot be explained by simple magnetic impurities. The ferromagnetism is unique to hydrogenated epitaxial graphene on SiC, where interactions with the interfacial buffer layer play a crucial role. We argue that the origin of the observed ferromagnetism is governed by electron correlation effects of the narrow Si dangling bond states in the buffer layer exchange coupled to localized states in the hydrogenated graphene layer. This forms a quasi-three-dimensional ferromagnet with a Curie temperature higher than 300 K.

Graphene; Feromagnetism; SiC; Intercalation

Graphene; Feromagnetism; SiC; Intercalation

GIESBERS, A.; UHLÍŘOVÁ, K.; KONEČNÝ, M.; PETERS, E.; BURKHARD, M.; AARTS, J.; FLIPSE, C.

2014

18.10.2013

0031-9007

PHYSICAL REVIEW LETTERS

111

16

Spojené státy americké

166101-1

166101-5

5