Detail publikace

Feasibility of direct analysis of algae contamination with chromium and copper on the filter with laser-induced breakdown spectroscopy and laser ablation inductively coupled plasma mass spectrometry

HRDLIČKA, A. HEGROVÁ, J. BUČKOVÁ, M. PROCHAZKA, D. HOLÁ, M. NOVOTNÝ, K. POŘÍZKA, P. KANICKÝ, V. KAISER, J.

Originální název

Feasibility of direct analysis of algae contamination with chromium and copper on the filter with laser-induced breakdown spectroscopy and laser ablation inductively coupled plasma mass spectrometry

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

The chromium and copper contamination of algae on a filter was directly monitored with laser-induced breakdown spectroscopy (LIBS) as a demonstration of LIBS capabilities. Liquid samples of the green alga Des-modesmus subspicatus were intentionally contaminated with chromium, incubated, filtered, and the filters with the algae were analysed. Inductively coupled plasma mass spectrometry (ICP-MS) was used as a reference method. One half of the filter with the algae was dissolved and analysed as a solution with ICP-MS and the second half was subjected to the LIBS and laser ablation-ICP-MS analysis. Chromium and copper were attributable to the algae contamination and detectable with LIBS. The results from the LIBS provided almost equivalent information about the relative changes of the Cr and Cu concentration in the algae. The sensitivity of LIBS with a Czerny-Turner spectrometer was fully comparable with the ICP-MS procedure. The trends from LIBS were more similar to the LA-ICP-MS ones. It means that the algae growth inhibition in dependence on the chromium or copper content can be alternatively monitored with LIBS instead of the complicated decomposition procedure in ICP-MS analysis.

Klíčová slova

Laser-induced breakdown spectroscopy; Laser ablation; Inductively coupled plasma; Mass spectrometry; Algae; Filter

Autoři

HRDLIČKA, A.; HEGROVÁ, J.; BUČKOVÁ, M.; PROCHAZKA, D.; HOLÁ, M.; NOVOTNÝ, K.; POŘÍZKA, P.; KANICKÝ, V.; KAISER, J.

Vydáno

1. 9. 2022

Nakladatel

PERGAMON-ELSEVIER SCIENCE LTD

Místo

OXFORD

ISSN

1873-3565

Periodikum

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY

Ročník

195

Číslo

1

Stát

Spojené království Velké Británie a Severního Irska

Strany od

106488

Strany do

106495

Strany počet

8

URL

https://www.sciencedirect.com/science/article/pii/S058485472200132X?via%3Dihub

BibTex

@article{BUT179163,
  author="Aleš {Hrdlička} and Jitka {Hegrová} and Martina {Bučková} and David {Prochazka} and Markéta {Holá} and Karel {Novotný} and Pavel {Pořízka} and Viktor {Kanický} and Jozef {Kaiser}",
  title="Feasibility of direct analysis of algae contamination with chromium and copper on the filter with laser-induced breakdown spectroscopy and laser ablation inductively coupled plasma mass spectrometry",
  journal="SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY",
  year="2022",
  volume="195",
  number="1",
  pages="8",
  doi="10.1016/j.sab.2022.106488",
  issn="1873-3565",
  url="https://www.sciencedirect.com/science/article/pii/S058485472200132X?via%3Dihub"
}