Densification of Magnesium Aluminate Spinel Using Manganese and Cobalt Fluoride as Sintering Aids

Densification of Magnesium Aluminate Spinel Using Manganese and Cobalt Fluoride as Sintering Aids

Článek WoS

Highly dense magnesium aluminate spinel bodies are usually fabricated using pressure-assisted methods, such as spark plasma sintering (SPS), in the presence of lithium fluoride as a sintering aid. The present work investigates whether the addition of transition metal fluorides promotes the sintering of MgAl2O4 bodies during SPS. At the same time, such fluorides can act as a source of optically active dopants. A commercial MgAl2O4 was mixed with 0.5 wt% of LiF, MnF2, and CoF2 and, afterwards, consolidated using SPS at 1400 degrees C. Although MnF2 and CoF2 promote the densification as effectively as LiF, they cause significant grain growth.

Highly dense magnesium aluminate spinel bodies are usually fabricated using pressure-assisted methods, such as spark plasma sintering (SPS), in the presence of lithium fluoride as a sintering aid. The present work investigates whether the addition of transition metal fluorides promotes the sintering of MgAl2O4 bodies during SPS. At the same time, such fluorides can act as a source of optically active dopants. A commercial MgAl2O4 was mixed with 0.5 wt% of LiF, MnF2, and CoF2 and, afterwards, consolidated using SPS at 1400 degrees C. Although MnF2 and CoF2 promote the densification as effectively as LiF, they cause significant grain growth.

MgAl2O4; lithium fluoride; cobalt fluoride; manganese fluoride; spark plasma sintering; grain growth

MgAl2O4; lithium fluoride; cobalt fluoride; manganese fluoride; spark plasma sintering; grain growth

TALIMIAN, A.; POUCHLÝ, V.; MACA, K.; GALUSEK, D.

2021

01.01.2020

MDPI

BASEL

1996-1944

Materials

13

1

Švýcarská konfederace

102-1

102-10

10

https://www.mdpi.com/1996-1944/13/1/102

http://hdl.handle.net/11012/193416

materials-13-00102