Detail publikace

Universal approach for diffusion quantification applied to lead halide perovskite single crystals

POSPÍŠIL, J. MARÁČKOVÁ, L. ZMEŠKAL, O. KOVALENKO, A.

Originální název

Universal approach for diffusion quantification applied to lead halide perovskite single crystals

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

A universal approach to calculating diffusion coefficients in lead halide perovskite single crystals, which have ionic and mixed ionic–electronic conductivity, is proposed. Using impedance spectroscopy, it is demonstrated how to model a non-ideal Warburg element and transmission line equivalent circuit to identify ionic diffusion in the material. The proposed method is applicable to samples of any thickness and electrical properties. Additionally, it is shown how to overcome the challenges of low-frequency impedance measurement and the non-ideal behavior of the elements through extrapolative modeling and approximation.

Klíčová slova

Impedance spectroscopy; diffusion; Warburg; lead halide perovskite

Autoři

POSPÍŠIL, J.; MARÁČKOVÁ, L.; ZMEŠKAL, O.; KOVALENKO, A.

Vydáno

19. 1. 2023

Nakladatel

Springer

Místo

Switzerland

ISSN

0947-8396

Periodikum

Applied Physics A

Ročník

129

Číslo

1

Stát

Spolková republika Německo

Strany od

1

Strany do

8

Strany počet

8

URL

Plný text v Digitální knihovně

BibTex

@article{BUT181642,
  author="Jan {Pospíšil} and Lucie {Maráčková} and Oldřich {Zmeškal} and Alexander {Kovalenko}",
  title="Universal approach for diffusion quantification applied to lead halide perovskite single crystals",
  journal="Applied Physics A",
  year="2023",
  volume="129",
  number="1",
  pages="1--8",
  doi="10.1007/s00339-023-06398-3",
  issn="0947-8396",
  url="https://link.springer.com/article/10.1007/s00339-023-06398-3"
}