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Original title in Czech: Fyzikální chemieFCHAbbreviation: DPCPO_FCH_4Acad. year: 2013/2014
Programme: Physical Chemistry
Length of Study:
Accredited from: 16.10.2009Accredited until: 31.12.2015
Guarantor
prof. Ing. Miloslav Pekař, CSc.
Issued topics of Doctoral Study Program
Supervisor: Klučáková Martina, prof. Ing., Ph.D.
Supervisor: Vala Martin, prof. Mgr., Ph.D.
Supervisor: Pekař Miloslav, prof. Ing., CSc.
computer simulation of transport of active substances in natural systems
Supervisor: Krčma František, prof. RNDr., Ph.D.
The work is focused on the study of pi-conjugated organic materials and the relationship between their chemical structure and electron processes. Goal is to identify the key parameters of materials and use of this knowledge in the design of new structures. The work also includes the design and preparation of the model devices and their characterization. Materials for the construction of organic solid-state lasers will be studied in particular. Attention will be also paid to the optical effects of higher order and photonic materials for other applications such as organic solar cells and light-emitting diodes. Electron processes in these substances will be studied mainly by optical spectroscopic methods including laser techniques and by optoelectrical and electrical methods.
Humic complexes will be prepared and tested in point of view their chemical and thermal analysis.
Supervisor: Weiter Martin, prof. Ing., Ph.D.
This work will be focused on a study of printed sensors for UV and visible light and UV and VIS dosimeters based on photocatalytical active titanium dioxide layers. This thesis will be a part of Technology Agency of the CR project.
Supervisor: Veselý Michal, prof. Ing., CSc.
Non-linear fluid models of rational thermodynamics as a subject of thermodynamically correct descritpion of their reaction kinetics.
The subject is focused on investigation of molecular and crystalline structure of organic semiconductors. It will contain crystal growth, measuring of x-ray diffractograms and hence calculation of the spatial arrangement of molecules and crystals and its consequence for the arrangement of molecular orbitals and charge transport. Simultaneously the auxiliary methods as electron microscopy, atomic force microscopy, infrared and Raman spectroscopy will be used. The context of the spatial arrangement with chemical stability and electrical properties will be searched.
Supervisor: Salyk Ota, doc. Ing., CSc.
This PhD. thesis would develop the well-known knowledge concerning applications of rational thermodynamics to the description of chemically reacting compounds with the accent to their kinetics and the practical applications (description of heterogenous systems, non-linear liquids of lower order). The scope itself would be based on applications of mathematical methods standardly used in the thermodynamics of continuum for description of chemically reagent systems (vector, tensor and functional analysis). Therefore a good knowledge of mathematics as the foundation for the studies is expected, see e.g. Samohýl I.: Racionální termodynamika chemicky reagujících směsí, Praha 1982; Šilhavý M.: The Mechanics and Thermodynamics of Continuous Media, Berlin 1997. The aim of the thesis is to find limits given by equations of thermodynamics and inequalities of the kinetics of chemical reactions in studied systems.
Supervisor: Tomáš Jiří, doc. RNDr., Dr.
The subject matter is focused on characterization of active layers of organic electronic devices (like OELD - Organic Electroluminescent Devices, FET - Field Effect Transistors, diodes and photovoltaic cells and sensors) by means of physical methods as IR and UV VIS absorption, luminescence, conductivity and environmental influences. The subject covers also basic deposition methods for thin films structures. Preferentially will be investigated derivatives of diketopyrrolo-pyrroles - DPP and their application properties with respect to collaboration with Research Institute for Organic Syntheses, Inc. and Synthesia, Inc., both in Pardubice, with respect to joint projects.