Course detail
Chemistry of Building Materials
FAST-CC51Acad. year: 2014/2015
Chemical bond, chemical equilibrium. Kinetics of chemical reactions. Thermal balance of chemical reaction. Water, ionization, pH. Chemistry of inorganic non-metallic materials - composition, properties and degradation. Chemistry and electrochemistry of metallic building materials, electrochemical potentials, corrosion of metals, and protection. Chemical properties of polymers, their stability and degradation. Biocorrosion of building materials.
Language of instruction
Number of ECTS credits
Mode of study
Guarantor
Department
Learning outcomes of the course unit
Metals and their chemical and electrochemical properties.
Chemical and biological degradation processes of cement composites, gypsum, lime binders, metals, plastics.
Modelling of degradation processes of concrete.
Water in building materials, composition, chemical and physical properties.
Student gets the aim of subject under control, i. e. chemical processes of the solid structure of inorganic binder forming, chemical properties of metals, plastics, and degradation processes of building materials, include modelling. Student learns the chemical and physical properties of water, the water transport, and negative effect on building materials. Student gets the basic overview on the properties of construction materials.
Prerequisites
Co-requisites
Planned learning activities and teaching methods
Assesment methods and criteria linked to learning outcomes
Course curriculum
2. Kinetics of chemical reaction. Thermal balance of chemical reaction.
3. Water – structure, ionization, pH, substances content in water, and their effect on building materials.
4. Porosity of building materials. Transport of water and salts.
5. Chemistry of gypsum and anhydrite binders, properties of hardened gypsum, and degradation.
6. Chemistry of lime binders, plasters and mortars, degradation, renovation of plasters.
7. Degradation of ceramics – composition, porous structure, crystallization pressure of salts in pores. Chemistry of glass, and corrosion.
8. Chemical properties of cement paste in concrete.
9. Degradation processes of cement paste in concrete caused by atmosphere and aggressive solutions.
10. Chemical properties of aggregates in concrete, degrading processes. Stability and degradation of fibre reinforcement.
11. Chemistry of polymers based on carbon and silicon chains. Degradation of polymers.
12. Electrochemical properties of metals, electrochemical potentials. Metal corrosion. Corrosion of steel reinforcement in concrete, in water, soil corrosion, atmospheric corrosion.
13. Biocorrosion of building materials – fungi, alga, bacteria. Protection to corrosion and degradation of building materials.
Work placements
Aims
Specification of controlled education, way of implementation and compensation for absences
Recommended optional programme components
Prerequisites and corequisites
Basic literature
Scrivener, K.L., Young , J.F.: Mechanisms of Chemical Degradation of Cement-based Systems. Spon Press, 1997. (EN)
Recommended reading
Taylor, H.F.W.: Cement Chemistry. Thomas Telford, 1997. (EN)
Classification of course in study plans
Type of course unit
Lecture
Teacher / Lecturer
Syllabus
2. Kinetics of chemical reaction. Thermal balance of chemical reaction.
3. Water – structure, ionization, pH, substances content in water, and their effect on building materials.
4. Porosity of building materials. Transport of water and salts.
5. Chemistry of gypsum and anhydrite binders, properties of hardened gypsum, and degradation.
6. Chemistry of lime binders, plasters and mortars, degradation, renovation of plasters.
7. Degradation of ceramics – composition, porous structure, crystallization pressure of salts in pores. Chemistry of glass, and corrosion.
8. Chemical properties of cement paste in concrete.
9. Degradation processes of cement paste in concrete caused by atmosphere and aggressive solutions.
10. Chemical properties of aggregates in concrete, degrading processes. Stability and degradation of fibre reinforcement.
11. Chemistry of polymers based on carbon and silicon chains. Degradation of polymers.
12. Electrochemical properties of metals, electrochemical potentials. Metal corrosion. Corrosion of steel reinforcement in concrete, in water, soil corrosion, atmospheric corrosion.
13. Biocorrosion of building materials – fungi, alga, bacteria. Protection to corrosion and degradation of building materials.
Exercise
Teacher / Lecturer
Syllabus
Salinity of masonry, adjustment of salts and deep of penetrating into testing material
Water, determination of ions in water, argentometric determination of chlorides
Binders, adjustment the type of binder according to present elements, deetrminatio of sulphste in solution
Analysis of cement, decomposition of cement, determination of MnO in blended cement
Analysis of cement, determination of CaO and MgO, decomposition of sample for determination of sulphates, determination of SiO2
Analysis of cement, determination of Fe2O3 and Al2O3, filtration of precipitate of BaSO4
Analysis of cement, determination of TiO2 and P2O5, annealing of precipitate of BaSO4
Corrosion of concrete, determination of Ca(OH)2 in cement pastes, adjustment of carobated and non-carbonated cement paste
Determination of aggressive CO2 in water, determination of ammonium ions in water
Silicium, preparing of silicium using magnesium as reducing agent, solubility of silicium in alkaline solutions, preparation of borosilicate glass
Supervision of protocols, credit