Publication result detail

Cobalt Doped LiFePO4/C Composite Material for Li-Ion Cathodes

ČECH, O.; THOMAS, J.; SEDLAŘÍKOVÁ, M.; VONDRÁK, J.; VISINTIN, A.

Original Title

Cobalt Doped LiFePO4/C Composite Material for Li-Ion Cathodes

English Title

Cobalt Doped LiFePO4/C Composite Material for Li-Ion Cathodes

Type

Peer-reviewed article not indexed in WoS or Scopus

Original Abstract

High temperature solid state synthesis was used for preparation of LiFePO4/C composite material and cobalt doped LiFePO4/C composite material. Glycine assisted combustion method was involved as a carbon coating procedure. It uses glycine as a carbon precursor for conductive coating and connecting of active material nanoparticles. Two different samples were prepared and investigated - clear LiFePO4/C material and LiFePO4/C doped with 1% of cobalt. The aim of this work is to show how a supervalent ion of cobalt influences parameters of cathode material. Electrochemical characterization by galvanostatic cycling, electrochemical impedance spectroscopy and rate capability was made and physical characterization by SEM, TEM and X-ray diffraction was provided.

English abstract

High temperature solid state synthesis was used for preparation of LiFePO4/C composite material and cobalt doped LiFePO4/C composite material. Glycine assisted combustion method was involved as a carbon coating procedure. It uses glycine as a carbon precursor for conductive coating and connecting of active material nanoparticles. Two different samples were prepared and investigated - clear LiFePO4/C material and LiFePO4/C doped with 1% of cobalt. The aim of this work is to show how a supervalent ion of cobalt influences parameters of cathode material. Electrochemical characterization by galvanostatic cycling, electrochemical impedance spectroscopy and rate capability was made and physical characterization by SEM, TEM and X-ray diffraction was provided.

Keywords

lithium, ion, LiFePO4, cobalt, XRD, glycine, combustion

Key words in English

lithium, ion, LiFePO4, cobalt, XRD, glycine, combustion

Authors

ČECH, O.; THOMAS, J.; SEDLAŘÍKOVÁ, M.; VONDRÁK, J.; VISINTIN, A.

RIV year

2013

Released

21.06.2012

ISBN

1938-6737

Periodical

ECS Transaction

Volume

40

Number

1

State

United States of America

Pages from

93

Pages to

97

Pages count

5

BibTex

@article{BUT92625,
  author="Ondřej {Čech} and Jorge {Thomas} and Marie {Sedlaříková} and Jiří {Vondrák} and Arnaldo {Visintin}",
  title="Cobalt Doped LiFePO4/C Composite Material for Li-Ion Cathodes",
  journal="ECS Transaction",
  year="2012",
  volume="40",
  number="1",
  pages="93--97",
  issn="1938-6737"
}