Publication result detail

Pink Afterglow in Nitrogen - Hydrocarbon Mixtures

Krčma, F.

Original Title

Pink Afterglow in Nitrogen - Hydrocarbon Mixtures

English Title

Pink Afterglow in Nitrogen - Hydrocarbon Mixtures

Type

Peer-reviewed article not indexed in WoS or Scopus

Original Abstract

The effect of the nitrogen pink afterglow quenching by hydrocarbon traces is studied in the flowing afterglow regime. The Pyrex wall temperature around the observation point was varied between the ambient and liquid nitrogen temperature. The spectra of nitrogen first and second positive and first negative bands and CN violet and red systems were observed. The strong quenching of the vibrational populations of the nitrogen N2(B), N2(C) and N2+(B) states was observed and this effect increases with the decreasing wall temperature. The vibrational populations of CN(A) and CN(B) states are more or less independent of the hydrocarbon concentration at the ambient wall temperature, but they increase with the decreasing temperature. A simplified kinetic model of the processes at our experimental condition is presented, too.

English abstract

The effect of the nitrogen pink afterglow quenching by hydrocarbon traces is studied in the flowing afterglow regime. The Pyrex wall temperature around the observation point was varied between the ambient and liquid nitrogen temperature. The spectra of nitrogen first and second positive and first negative bands and CN violet and red systems were observed. The strong quenching of the vibrational populations of the nitrogen N2(B), N2(C) and N2+(B) states was observed and this effect increases with the decreasing wall temperature. The vibrational populations of CN(A) and CN(B) states are more or less independent of the hydrocarbon concentration at the ambient wall temperature, but they increase with the decreasing temperature. A simplified kinetic model of the processes at our experimental condition is presented, too.

Keywords

nitrogen afterglow, pink afterglow, CN chemiluminiscence, nitrogen kinetics

Key words in English

nitrogen afterglow, pink afterglow, CN chemiluminiscence, nitrogen kinetics

Authors

Krčma, F.

Released

01.10.2005

Publisher

Slovenská akadémia ved

Location

Bratislava

ISBN

0323-0465

Periodical

Acta Physica Slovaca

Volume

55

Number

5

State

Slovak Republic

Pages from

453

Pages to

460

Pages count

8

BibTex

@article{BUT42436,
  author="František {Krčma}",
  title="Pink Afterglow in Nitrogen - Hydrocarbon Mixtures",
  journal="Acta Physica Slovaca",
  year="2005",
  volume="55",
  number="5",
  pages="453--460",
  issn="0323-0465"
}