Magnetic phase dependency of the thermal conductivity of FeRh from thermoreflectance experiments and numerical simulations

Magnetic phase dependency of the thermal conductivity of FeRh from thermoreflectance experiments and numerical simulations

WoS Article

FeRh is well known in its bulk form for a temperature-driven antiferromagnetic (AFM) to ferromagnetic (FM) transition near room temperature. It has aroused renewed interest in its thin-film form, with particular focus on its biaxial AFM magnetic anisotropy which could serve for data encoding, and the possibility to investigate laserassisted phase transitions, with varying contributions from electrons, phonons, and magnons. In order to estimate the typical temperature increase occurring in these experiments, we performed modulated thermoreflectance microscopy to determine the thermal conductivity kappa of FeRh. As often occurs upon alloying, and despite the good crystallinity of the layer, kappa was found to be lower than the thermal conductivities of its constituting elements. More unexpectedly, given the electrically more conducting nature of the FM phase, it turned out to be three times lower in the FM phase compared to the AFM phase. This trend was confirmed by examining the temporal decay of incoherent phonons generated by a pulsed laser in both phases. To elucidate these results, first- and second-principles simulations were performed to estimate the phonon, magnon, and electron contributions to the thermal conductivity. They were found to be of the same order of magnitude, and to give a quantitative rendering of the experimentally observed kappa AFM. In the FM phase, however, simulations overestimate the low experimental values, implying very different (shorter) electron and magnon lifetimes.

FeRh is well known in its bulk form for a temperature-driven antiferromagnetic (AFM) to ferromagnetic (FM) transition near room temperature. It has aroused renewed interest in its thin-film form, with particular focus on its biaxial AFM magnetic anisotropy which could serve for data encoding, and the possibility to investigate laserassisted phase transitions, with varying contributions from electrons, phonons, and magnons. In order to estimate the typical temperature increase occurring in these experiments, we performed modulated thermoreflectance microscopy to determine the thermal conductivity kappa of FeRh. As often occurs upon alloying, and despite the good crystallinity of the layer, kappa was found to be lower than the thermal conductivities of its constituting elements. More unexpectedly, given the electrically more conducting nature of the FM phase, it turned out to be three times lower in the FM phase compared to the AFM phase. This trend was confirmed by examining the temporal decay of incoherent phonons generated by a pulsed laser in both phases. To elucidate these results, first- and second-principles simulations were performed to estimate the phonon, magnon, and electron contributions to the thermal conductivity. They were found to be of the same order of magnitude, and to give a quantitative rendering of the experimentally observed kappa AFM. In the FM phase, however, simulations overestimate the low experimental values, implying very different (shorter) electron and magnon lifetimes.

IRON-RHODIUM; TRANSITION; TEMPERATURE; RESISTANCE; SPECTRUM; IRIDIUM; ALLOYS; HEAT

IRON-RHODIUM; TRANSITION; TEMPERATURE; RESISTANCE; SPECTRUM; IRIDIUM; ALLOYS; HEAT

Castellano, A.; Alhada-Lahbabi, K.; Arregi, JA.; Uhlir, V.; Perrin, B.; Gourdon, C.; Fournier, D.; Verstraete, MJ.; Thevenard, L.

2025

28.08.2024

AMER PHYSICAL SOC

COLLEGE PK

2475-9953

Physical Review Materials

8

8

United States of America

14

https://journals.aps.org/prmaterials/abstract/10.1103/PhysRevMaterials.8.084411