Publication detail

Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry

Yu, Zhang Ahmad, Muhammad Sajjad Shen, Boxiong Li, Yingna Ibrahim, Muhammad Bokhari, Awais Klemes, Jiri Jaromir

Original Title

Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry

Type

journal article in Web of Science

Language

English

Original Abstract

The bioenergy potential of waste textile cotton cellulose (BOC) and the activated waste textile cotton cellulose by H3PO4 (BOP) were assessed in this study. BOC and BOP were pyrolyzed in TG at four heating rates. The thermal weight-loss process of BOC and BOP can be separated into drying stage, rapid pyrolysis stage and carbonization stage. The kinetic and thermodynamic parameters of the pyrolysis reaction were evaluated using an iso-conversion model. The Ea, Delta H and Delta G values of BOC are 84.79-206.79 kJ mol(-1), 159.85-318.88 kJ mol(-1) and 357.72-359.16 kJ mol-1, respectively. The Ea, & UDelta;H and & UDelta;G values of BOP are 101.81-453.85 kJ mol -1, 169.11-389.47 kJ mol-1 and 257 similar to 335.78 kJ mol-1, respectively. Py-GC/MS analysis illustrated that the peak area percentages of the products of BOC/BOP, including Glucopyranose, Ketones, Cycloalkane, Aromatic, Furan, Aliphatic, CO2, and others, were 47.7%/5%, 4.66%/30.41%, 0%/27.12%, 16.64%/3.22%, 8.55%/12.44%, 12.75%/13.29%, 4.19%/3.91% and 5.51%/4.61%, respectively. Compared with BOC, the low-quality products of BOP, Glucopyranose and Aromatic, decreased from 47.7% to 16.64%-5% and 3.22%, respectively, and the high-quality products, Ketone and Cycloalkane, increased from 4.66% to 0%-30.41% and 27.12%, respectively. The complexity of bio-oil of BOP is reduced, which gives a positive prospect for the purification of backward position.

Keywords

Kinetic parameters; Py-GC/MS; Pyrolysis; Thermodynamic analysis; Waste textile cotton cellulose

Authors

Yu, Zhang; Ahmad, Muhammad Sajjad; Shen, Boxiong; Li, Yingna; Ibrahim, Muhammad; Bokhari, Awais; Klemes, Jiri Jaromir

Released

15. 11. 2023

Publisher

PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

Location

PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

ISBN

0360-5442

Periodical

Energy

Number

283

State

United Kingdom of Great Britain and Northern Ireland

Pages count

12

URL

https://www.sciencedirect.com/science/article/pii/S0360544223017358?via%3Dihub

BibTex

@article{BUT187483,
  author="Yu, Zhang and Ahmad, Muhammad Sajjad and Shen, Boxiong and Li, Yingna and Ibrahim, Muhammad and Bokhari, Awais and Klemes, Jiri Jaromir",
  title="Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry",
  journal="Energy",
  year="2023",
  number="283",
  pages="12",
  doi="10.1016/j.energy.2023.128341",
  issn="0360-5442",
  url="https://www.sciencedirect.com/science/article/pii/S0360544223017358?via%3Dihub"
}