Modeling of argon-steam thermal plasma flow for abatement of fluorinated compounds

Modeling of argon-steam thermal plasma flow for abatement of fluorinated compounds

WoS Article

This study presents a numerical model of the hybrid-stabilized argon-steam thermal DC plasma torch of a new design for generating an argon-steam plasma suitable for efficient abatement of persistent perfluorinated compounds. The model includes the discharge region and the plasma jet flowing to the surrounding steam atmosphere contained in a plasma-chemical chamber. Compared to previous studies, the torch had a smaller nozzle diameter (5.3 mm) and a reduced input power (20-40 kW) and arc current (120-220 A). The outlet region for the plasma jet extends to 20 cm downstream of the exit nozzle. Fluid dynamic and thermal characteristics together with diffusion of argon, hydrogen and oxygen species, and distribution of plasma species in the discharge and the plasma jet are obtained for currents from 120 to 220 A. The results of the calculations show that the plasma jet exhibits high spatiotemporal fluctuations in the shear layer between the plasma jet and colder steam atmosphere. The most abundant species in the plasma jet are hydrogen and oxygen atoms near the jet center, and molecules of H-2, O-2 and OH in colder surrounding regions. Satisfactory agreement is obtained with measurements of the radial temperature and electron number density profiles near the jet center close to the nozzle exit.

This study presents a numerical model of the hybrid-stabilized argon-steam thermal DC plasma torch of a new design for generating an argon-steam plasma suitable for efficient abatement of persistent perfluorinated compounds. The model includes the discharge region and the plasma jet flowing to the surrounding steam atmosphere contained in a plasma-chemical chamber. Compared to previous studies, the torch had a smaller nozzle diameter (5.3 mm) and a reduced input power (20-40 kW) and arc current (120-220 A). The outlet region for the plasma jet extends to 20 cm downstream of the exit nozzle. Fluid dynamic and thermal characteristics together with diffusion of argon, hydrogen and oxygen species, and distribution of plasma species in the discharge and the plasma jet are obtained for currents from 120 to 220 A. The results of the calculations show that the plasma jet exhibits high spatiotemporal fluctuations in the shear layer between the plasma jet and colder steam atmosphere. The most abundant species in the plasma jet are hydrogen and oxygen atoms near the jet center, and molecules of H-2, O-2 and OH in colder surrounding regions. Satisfactory agreement is obtained with measurements of the radial temperature and electron number density profiles near the jet center close to the nozzle exit.

hybrid-stabilized electric arc; combined diffusion coefficients; inhomogeneous mixing; mole fraction; plasma species

hybrid-stabilized electric arc; combined diffusion coefficients; inhomogeneous mixing; mole fraction; plasma species

JENIŠTA, J.; CHAU, S.; CHIEN, S.; ŽIVNÝ, O.; TAKANA, H.; NISHIYAMA, H.; BARTLOVÁ, M.; AUBRECHT, V.; MURPHY, A.

2023

04.07.2022

IOP Publishing Ltd

BRISTOL

0022-3727

JOURNAL OF PHYSICS D-APPLIED PHYSICS

55

37

United Kingdom of Great Britain and Northern Ireland

1

20

20

https://iopscience.iop.org/article/10.1088/1361-6463/ac7aee

http://hdl.handle.net/