Publication result detail

Co(II) single-ion magnets: synthesis, structure, and magnetic properties

JURÁKOVÁ, J.; ŠALITROŠ, I.

Original Title

Co(II) single-ion magnets: synthesis, structure, and magnetic properties

English Title

Co(II) single-ion magnets: synthesis, structure, and magnetic properties

Type

WoS Article

Original Abstract

Magnetoactive coordination compounds exhibiting bi- or multistability between two or more magnetic stable states present an attractive example of molecular switches. Currently, the research is focused on molecular nanomagnets, especially single molecule magnets (SMMs), which are molecules, where the slow relaxation of the magnetization based on the purely molecular origin is observed. Contrary to ferromagnets, the magnetic bistability of SMMs does not require intermolecular interactions, which makes them particularly interesting in terms of application potential, especially in the high-density storage of data. This paper aims to introduce the readers into a basic understanding of SMM behaviour, and furthermore, it provides an overview of the attractive Co(II) SMMs with emphasis on the relation between structural features, magnetic anisotropy, and slow relaxation of magnetization in tetra-, penta-, and hexacoordinate complexes. [GRAPHICS] .

English abstract

Magnetoactive coordination compounds exhibiting bi- or multistability between two or more magnetic stable states present an attractive example of molecular switches. Currently, the research is focused on molecular nanomagnets, especially single molecule magnets (SMMs), which are molecules, where the slow relaxation of the magnetization based on the purely molecular origin is observed. Contrary to ferromagnets, the magnetic bistability of SMMs does not require intermolecular interactions, which makes them particularly interesting in terms of application potential, especially in the high-density storage of data. This paper aims to introduce the readers into a basic understanding of SMM behaviour, and furthermore, it provides an overview of the attractive Co(II) SMMs with emphasis on the relation between structural features, magnetic anisotropy, and slow relaxation of magnetization in tetra-, penta-, and hexacoordinate complexes. [GRAPHICS] .

Keywords

Coordination chemistry; Molecular magnets; Magnetic properties; Coordination geometry

Key words in English

Coordination chemistry; Molecular magnets; Magnetic properties; Coordination geometry

Authors

JURÁKOVÁ, J.; ŠALITROŠ, I.

RIV year

2023

Released

01.11.2022

Publisher

SPRINGER WIEN

Location

WIEN

ISBN

1434-4475

Periodical

MONATSHEFTE FUR CHEMIE

Volume

153

Number

11

State

Republic of Austria

Pages from

1001

Pages to

1036

Pages count

36

URL

https://link.springer.com/article/10.1007/s00706-022-02920-0

BibTex

@article{BUT178461,
  author="Jana {Juráková} and Ivan {Šalitroš}",
  title="Co(II) single-ion magnets: synthesis, structure, and magnetic properties",
  journal="MONATSHEFTE FUR CHEMIE",
  year="2022",
  volume="153",
  number="11",
  pages="1001--1036",
  doi="10.1007/s00706-022-02920-0",
  issn="0026-9247",
  url="https://link.springer.com/article/10.1007/s00706-022-02920-0"
}