Publication result detail

Lanthanide-Based Metal-Organic-Frameworks for Proton Conduction and Magnetic Properties

BISWAS, S.; NEUGEBAUER, P.

Original Title

Lanthanide-Based Metal-Organic-Frameworks for Proton Conduction and Magnetic Properties

English Title

Lanthanide-Based Metal-Organic-Frameworks for Proton Conduction and Magnetic Properties

Type

WoS Article

Original Abstract

The coexistence of proton conductivity and magnetic properties in metal organic frameworks (MOFs) is simply an attractive prospect to design and create multifunctional molecular materials. However, the simultaneity of interesting magnetic properties (eg. magnetocaloric effect, slow magnetic relaxation or magnetic ordering) and proton conduction in a MOF is very implausible to be observed, as chemical and structural necessities are absolutely poles apart for either of the properties. In this context, lanthanide-based metal-organic frameworks (LMOFs) have emerged as an intriguing class of materials to observe such coexistence in few cases. In this perspective, the advantages of combining lanthanide ions and organic acids as ligands to construct a proton-conductive magnetic metal organic framework are briefly discussed. The current status of this specific research area regarding some fascinating LMOFs exhibiting proton conductivity and magnetic properties is reviewed in detail. Also, a future perspective of such materials is discussed.

English abstract

The coexistence of proton conductivity and magnetic properties in metal organic frameworks (MOFs) is simply an attractive prospect to design and create multifunctional molecular materials. However, the simultaneity of interesting magnetic properties (eg. magnetocaloric effect, slow magnetic relaxation or magnetic ordering) and proton conduction in a MOF is very implausible to be observed, as chemical and structural necessities are absolutely poles apart for either of the properties. In this context, lanthanide-based metal-organic frameworks (LMOFs) have emerged as an intriguing class of materials to observe such coexistence in few cases. In this perspective, the advantages of combining lanthanide ions and organic acids as ligands to construct a proton-conductive magnetic metal organic framework are briefly discussed. The current status of this specific research area regarding some fascinating LMOFs exhibiting proton conductivity and magnetic properties is reviewed in detail. Also, a future perspective of such materials is discussed.

Keywords

Lanthanides; Magnetic properties; Magnetic refrigeration; Metal-organic frameworks; Proton conductivity

Key words in English

Lanthanides; Magnetic properties; Magnetic refrigeration; Metal-organic frameworks; Proton conductivity

Authors

BISWAS, S.; NEUGEBAUER, P.

RIV year

2022

Released

07.12.2021

Publisher

Wiley-VCH

Location

WEINHEIM

ISBN

1099-0682

Periodical

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Volume

2021

Number

45

State

Federal Republic of Germany

Pages from

4610

Pages to

4618

Pages count

9

URL

https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100686

Full text in the Digital Library

http://hdl.handle.net/11012/204010

BibTex

@article{BUT174922,
  author="Soumava {Biswas} and Petr {Neugebauer}",
  title="Lanthanide-Based Metal-Organic-Frameworks for Proton Conduction and Magnetic Properties",
  journal="EUROPEAN JOURNAL OF INORGANIC CHEMISTRY",
  year="2021",
  volume="2021",
  number="45",
  pages="4610--4618",
  doi="10.1002/ejic.202100686",
  issn="1434-1948",
  url="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100686"
}

Documents

Biswas_2021