Publication result detail

Co doped YbFeO3: exploring the electrical properties via tuning the doping level

POLAT, Ö.; COSKUN, M; COSKUN, F. M.; ZLÁMAL, J.; ZENGIN KURT, B.; DORMUS, Z., CAGLAR, M.; TURUT, A.

Original Title

Co doped YbFeO3: exploring the electrical properties via tuning the doping level

English Title

Co doped YbFeO3: exploring the electrical properties via tuning the doping level

Type

WoS Article

Original Abstract

The magnetic and electrical features of rare-earth orthoferrites, RFeO3, can be modified via substitution of different elements into R and/or Fe sites. In the present investigation, the electrical properties of YbFeO3 (YbFO) were inspected with cobalt (Co) doping into Fe sites by various mole %. The crystalline morphology of the obtained YbFeO3 and YbFe1-xCoxO3 (YbFCO) (x=0.01, 0.05, 0.10) powders was studied by X-ray diffractometer (XRD) and infrared (IR) spectroscopy measurements. Surface structure of the obtained powders was scrutinized by scanning electron microscope (SEM). Furthermore, X-ray photoelectron spectroscopy (XPS) was employed for identifying the oxidation states of the synthesized components. Dielectric/impedance spectroscopy measurements were conducted to investigate electrical features of the YbFO and YbFCO powders at different frequencies and temperatures. It turned out that the conductivity and the dielectric constant of undoped YbFO can be boosted by Co doping into Fe sites. The present study underscored that multiple models need to be taken into account for the studied materials to explain conduction mechanism.

English abstract

The magnetic and electrical features of rare-earth orthoferrites, RFeO3, can be modified via substitution of different elements into R and/or Fe sites. In the present investigation, the electrical properties of YbFeO3 (YbFO) were inspected with cobalt (Co) doping into Fe sites by various mole %. The crystalline morphology of the obtained YbFeO3 and YbFe1-xCoxO3 (YbFCO) (x=0.01, 0.05, 0.10) powders was studied by X-ray diffractometer (XRD) and infrared (IR) spectroscopy measurements. Surface structure of the obtained powders was scrutinized by scanning electron microscope (SEM). Furthermore, X-ray photoelectron spectroscopy (XPS) was employed for identifying the oxidation states of the synthesized components. Dielectric/impedance spectroscopy measurements were conducted to investigate electrical features of the YbFO and YbFCO powders at different frequencies and temperatures. It turned out that the conductivity and the dielectric constant of undoped YbFO can be boosted by Co doping into Fe sites. The present study underscored that multiple models need to be taken into account for the studied materials to explain conduction mechanism.

Keywords

YbFeO3; Cobalt doping; Solid-state reaction; Powder; Electric modulus; Dielectric constant; Conductivity

Key words in English

YbFeO3; Cobalt doping; Solid-state reaction; Powder; Electric modulus; Dielectric constant; Conductivity

Authors

POLAT, Ö.; COSKUN, M; COSKUN, F. M.; ZLÁMAL, J.; ZENGIN KURT, B.; DORMUS, Z., CAGLAR, M.; TURUT, A.

RIV year

2020

Released

15.03.2019

Publisher

SPRINGER HEIDELBERG

Location

HEIDELBERG

ISBN

0947-7047

Periodical

IONICS

Volume

25

Number

8

State

Federal Republic of Germany

Pages from

4013

Pages to

4029

Pages count

17

URL

https://link.springer.com/article/10.1007%2Fs11581-019-02934-5

BibTex

@article{BUT161926,
  author="POLAT, Ö. and COSKUN, M and COSKUN, F. M. and ZLÁMAL, J. and ZENGIN KURT, B. and DORMUS, Z., CAGLAR, M. and TURUT, A.",
  title="Co doped YbFeO3: exploring the electrical properties via tuning the doping level",
  journal="IONICS",
  year="2019",
  volume="25",
  number="8",
  pages="4013--4029",
  doi="10.1007/s11581-019-02934-5",
  issn="0947-7047",
  url="https://link.springer.com/article/10.1007%2Fs11581-019-02934-5"
}

Documents

Co Doped YbFeO3 Exploring the Electrical Properties via Tuning the Doping Level