Publication result detail

Light-induced non-Arrhenian conductivity of the single crystal methylammonium lead bromide perovskites

POSPÍŠIL, J.; ZMEŠKAL, O.; KRAJČOVIČ, J.; WEITER, M.; KOVALENKO, A.

Original Title

Light-induced non-Arrhenian conductivity of the single crystal methylammonium lead bromide perovskites

English Title

Light-induced non-Arrhenian conductivity of the single crystal methylammonium lead bromide perovskites

Type

WoS Article

Original Abstract

In the present communication, the conductivity of the single crystal methylammonium lead bromide as a function of temperature is studied. As a result, the activation energies for the dark/light conditions were determined. Interestingly, when the light illumination is applied, depending of the applied bias voltage, the complex conductivity response on the temperature changes was observed. Depending on the electrical field applied, the material follows two behaviors: first is typical of semiconductors and the second one and non-Arrhenian behavior, which is distinctive for metals. This is, for the best of our knowledge, the first observation of this unique property of single crystal methylammonium lead bromide perovskite.

English abstract

In the present communication, the conductivity of the single crystal methylammonium lead bromide as a function of temperature is studied. As a result, the activation energies for the dark/light conditions were determined. Interestingly, when the light illumination is applied, depending of the applied bias voltage, the complex conductivity response on the temperature changes was observed. Depending on the electrical field applied, the material follows two behaviors: first is typical of semiconductors and the second one and non-Arrhenian behavior, which is distinctive for metals. This is, for the best of our knowledge, the first observation of this unique property of single crystal methylammonium lead bromide perovskite.

Keywords

Lead Halide Perovskites; Inverse Temperature Crystallization; Semiconductor; Thermal properties

Key words in English

Lead Halide Perovskites; Inverse Temperature Crystallization; Semiconductor; Thermal properties

Authors

POSPÍŠIL, J.; ZMEŠKAL, O.; KRAJČOVIČ, J.; WEITER, M.; KOVALENKO, A.

RIV year

2020

Released

28.11.2019

Publisher

Elsevier Ltd

Location

The Boulevard, Kidlington, OX5 1GB, United Kingdom

ISBN

0038-1098

Periodical

SOLID STATE COMMUNICATIONS

Volume

307

Number

113811

State

United States of America

Pages from

1

Pages to

13

Pages count

13

URL

https://doi.org/10.1016/j.ssc.2019.113777

Full text in the Digital Library

http://hdl.handle.net/

BibTex

@article{BUT160620,
  author="Jan {Pospíšil} and Oldřich {Zmeškal} and Jozef {Krajčovič} and Martin {Weiter} and Alexander {Kovalenko}",
  title="Light-induced non-Arrhenian conductivity of the single crystal methylammonium lead bromide perovskites",
  journal="SOLID STATE COMMUNICATIONS",
  year="2019",
  volume="307",
  number="113811",
  pages="1--13",
  doi="10.1016/j.ssc.2019.113777",
  issn="0038-1098",
  url="https://doi.org/10.1016/j.ssc.2019.113777"
}

Documents

Light-induced non-Arrhenian conductivity (main text, web)