Publication result detail

Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

NEMEC, I.; SVOBODA, I.; HERCHEL, R.

Original Title

Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

English Title

Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

Type

WoS Article

Original Abstract

The synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA(2-) is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations.

English abstract

The synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA(2-) is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations.

Keywords

spin crossover; Schiff base ligands; iron (III) complex; structure; magnetism

Key words in English

spin crossover; Schiff base ligands; iron (III) complex; structure; magnetism

Authors

NEMEC, I.; SVOBODA, I.; HERCHEL, R.

RIV year

2020

Released

02.08.2019

Publisher

MDPI

ISBN

2075-4701

Periodical

Metals

Volume

9

Number

8

State

Swiss Confederation

Pages from

1

Pages to

11

Pages count

11

URL

https://www.mdpi.com/2075-4701/9/8/849

Full text in the Digital Library

http://hdl.handle.net/11012/194809

BibTex

@article{BUT157945,
  author="Ivan {Nemec} and Ingrid {Svoboda} and Radovan {Herchel}",
  title="Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes",
  journal="Metals",
  year="2019",
  volume="9",
  number="8",
  pages="1--11",
  doi="10.3390/met9080849",
  url="https://www.mdpi.com/2075-4701/9/8/849"
}

Documents

metals-09-00849