Publication detail

Thermodynamics and digital simulation of intercalation processes

VONDRÁK, J., REITER, J., VELICKÁ, J., KLÁPŠTĚ, B., SEDLAŘÍKOVÁ, M., NOVÁK, V.

Original Title

Thermodynamics and digital simulation of intercalation processes

English Title

Thermodynamics and digital simulation of intercalation processes

Type

journal article - other

Language

en

Original Abstract

The insertion of guest particles into insertion and intercalation compounds is reconsidered from the viewpoint of reversible thermodynamics. A correlation between enthalpy of formation and volume changes is described, the latter being accessible from X-ray data. The phase changes caused by guest insertion are emphasized. Tungsten bronzes are used as model data.

English abstract

The insertion of guest particles into insertion and intercalation compounds is reconsidered from the viewpoint of reversible thermodynamics. A correlation between enthalpy of formation and volume changes is described, the latter being accessible from X-ray data. The phase changes caused by guest insertion are emphasized. Tungsten bronzes are used as model data.

Keywords

Intercalation, Insertion, Thermodynamics, Simulation, Diffusion

RIV year

2004

Released

10.01.2003

ISBN

1432-8488

Periodical

Journal of Solid State Electrochemistry

Year of study

7

Number

6

State

DE

Pages from

361

Pages to

367

Pages count

7

Documents

BibTex


@article{BUT41602,
  author="Jiří {Vondrák} and Jakub {Reiter} and Jana {Velická} and Břetislav {Klápště} and Marie {Sedlaříková} and Vítězslav {Novák}",
  title="Thermodynamics and digital simulation of intercalation processes",
  annote="The insertion of guest particles into insertion and intercalation compounds is reconsidered from the viewpoint of reversible thermodynamics. A correlation between enthalpy of formation and volume changes is described, the latter being accessible from X-ray data. The phase changes caused by guest insertion are emphasized. Tungsten bronzes are used as model data.",
  chapter="41602",
  journal="Journal of Solid State Electrochemistry",
  number="6",
  volume="7",
  year="2003",
  month="january",
  pages="361--367",
  type="journal article - other"
}