Publication detail

Accelerated carbonation of oil-well cement blended with pozzolans and latent hydraulic materials

KUZIELOVA, E. SLANÝ, M. ŽEMLIČKA, M. MÁSILKO, J.

Original Title

Accelerated carbonation of oil-well cement blended with pozzolans and latent hydraulic materials

Type

journal article in Web of Science

Language

English

Original Abstract

Accelerated carbonation of cement mixtures consisting of class G cement, silica fume, metakaolin, or blast furnace slag was studied by thermogravimetric, X-ray diffraction and Fourier transform infrared analyses for 1 year. Surface parts were fully carbonated during the first 7 days. Polymerization of amorphous hydrates due to their decalcification was observed together with the rising amount of calcium carbonates and reformation of gypsum from ettringite and monosulfate. Decalcification of clinker phases took place fast after the depletion of portlandite. Although portlandite was still present in unblended pastes, because of slower carbonation rate in the surface parts and higher C/S ratio of amorphous hydrates, the carbonation front moved inward during 3 months. Pozzolanic reactions in the samples with 30 mass% of additives depleted portlandite, however, higher amounts of C-(A)-S-H phases with lower C/S ratio, denser microstructure and faster carbonation of surface parts ensured their resistance against carbonation throughout the monitored period.

Keywords

Carbonation; Silica fume; Metakaolin; Ground-granulated blast-furnace slag

Authors

KUZIELOVA, E.; SLANÝ, M.; ŽEMLIČKA, M.; MÁSILKO, J.

Released

12. 8. 2023

Publisher

SPRINGER

Location

DORDRECHT

ISBN

1388-6150

Periodical

Journal of Thermal Analysis and Calorimetry

Year of study

148

Number

19

State

Hungary

Pages from

9963

Pages to

9977

Pages count

15

URL

Full text in the Digital Library

BibTex

@article{BUT187452,
  author="Eva {Kuzielova} and Michal {Slaný} and Matúš {Žemlička} and Jiří {Másilko}",
  title="Accelerated carbonation of oil-well cement blended with pozzolans and latent hydraulic materials",
  journal="Journal of Thermal Analysis and Calorimetry",
  year="2023",
  volume="148",
  number="19",
  pages="9963--9977",
  doi="10.1007/s10973-023-12378-9",
  issn="1388-6150",
  url="https://link.springer.com/content/pdf/10.1007/s10973-023-12378-9.pdf"
}