Publication detail

Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution

Ly, Nguyen Hoang Nguyen, Nguyen Binh Tran, Huynh Nhu Hoang, Thi Thuy Hang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Klemes, Jiri Jaromir

Original Title

Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution

Type

journal article in Web of Science

Language

English

Original Abstract

The motivation of the present study was a synthesis of the nanocomposites of UiO-66@ZnO/Biochar to embed carbendazim (CBZ) pesticide inside its porous structures for smart spraying and cleaner production. CBZ@UiO-66@ZnO/Biochar had the purpose of not only smart spraying to avoid releasing a large amount of CBZ into the groundwater but also of accurately delivering the CBZ pesticide to the desired grass/plant. High-resolution electron microscopy was introduced to characterise the morphologies of prepared composites with spatial elemental distribution mapping. X-ray diffraction (XRD) patterns and micro-Raman spectroscopy were employed for the crystal structures of UiO-66@ZnO. Spectral UV-Vis and Fourier transform-infrared (FT-IR) tools were utilized to estimate the UiO-66@ZnO/Biochar-based adsorption and release of CBZ into the dimethyl sulfoxide (DMSO)-water mixture. Our results indicated that the adsorption capacities of CBZ into the DMSO-water mixture onto UiO-66@ZnO and UiO-66@ZnO/Biochar nanocomposites were obtained at 68.8% and 72.6%. The half-life of photodegradation rate constants for CBZ@UiO-66@ZnO/Biochar was found to be 12.3 times longer than that of free CBZ. Notably, CBZ@UiO-66@ZnO/Biochar inhibitory concentration 50% (IC50) determination was estimated at 73.8 mu g/L and 209 mu g/L for Fusarium oxysporum and Aspergillus niger. This work provides a comprehensive experimental scheme for the chemisorption process of CBZ onto the UiO-66@ZnO/Biochar composite materials and the nanopesticide applications in sustainable agriculture towards cleaner productions.

Keywords

Biochar; Carbendazim; Cleaner production; Sustainable agriculture; UiO-66; ZnO

Authors

Ly, Nguyen Hoang; Nguyen, Nguyen Binh; Tran, Huynh Nhu; Hoang, Thi Thuy Hang; Joo, Sang-Woo; Vasseghian, Yasser; Kamyab, Hesam; Chelliapan, Shreeshivadasan; Klemes, Jiri Jaromir

Released

20. 5. 2023

Publisher

ELSEVIER SCI LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND

Location

ELSEVIER SCI LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND

ISBN

0959-6526

Periodical

Journal of Cleaner Production

Number

402

State

United Kingdom of Great Britain and Northern Ireland

Pages count

10

URL

https://www.sciencedirect.com/science/article/pii/S0959652623009678?via%3Dihub

BibTex

@article{BUT187517,
  author="Ly, Nguyen Hoang and Nguyen, Nguyen Binh and Tran, Huynh Nhu and Hoang, Thi Thuy Hang and Joo, Sang-Woo and Vasseghian, Yasser and Kamyab, Hesam and Chelliapan, Shreeshivadasan and Klemes, Jiri Jaromir",
  title="Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution",
  journal="Journal of Cleaner Production",
  year="2023",
  number="402",
  pages="10",
  doi="10.1016/j.jclepro.2023.136809",
  issn="0959-6526",
  url="https://www.sciencedirect.com/science/article/pii/S0959652623009678?via%3Dihub"
}