Publication detail

Macroscopic derivation of the kinetic mass-action law

PEKAŘ, M.

Original Title

Macroscopic derivation of the kinetic mass-action law

Type

journal article - other

Language

English

Original Abstract

Using several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.

Keywords

mass action, reaction rate, thermodynamic polynomial, thermodynamics

Authors

PEKAŘ, M.

RIV year

2010

Released

1. 1. 2010

Publisher

Springer-Verlag

ISBN

1878-5190

Periodical

Reaction Kinetics, Mechanisms and Catalysis

Year of study

99

Number

1

State

Hungary

Pages from

29

Pages to

35

Pages count

7

URL

http://link.springer.com/10.1007/s11144-009-0101-6

Full text in the Digital Library

http://hdl.handle.net/11012/19701

BibTex

@article{BUT48539,
  author="Miloslav {Pekař}",
  title="Macroscopic derivation of the kinetic mass-action law",
  journal="Reaction Kinetics, Mechanisms and Catalysis",
  year="2010",
  volume="99",
  number="1",
  pages="29--35",
  doi="10.1007/s11144-009-0101-6",
  issn="1878-5190",
  url="http://link.springer.com/10.1007/s11144-009-0101-6"
}