Publication detail

Oxygen activity in melts of Fe-C-Cr-Ni based alloys

ZÁDĚRA, A. DULAVA, M. PERNICA, V. KAŇA, V.

Original Title

Oxygen activity in melts of Fe-C-Cr-Ni based alloys

Type

journal article in Web of Science

Language

English

Original Abstract

Oxygen is an element that is first purposely brought into the steel melt to remove some unwanted elements or to reduce their concentration (oxidation). In the made cast steel there is on the contrary necessary to reduce the oxygen content with the use of deoxidation to such a level in order to avoid a reaction with carbon with the formation of CO bubbles. Concentration of oxygen in steel before casting is given, in particular, by the manner of metallurgical processing and the used deoxidation process. Oxygen is found in molten steels both as chemically bound in the form of oxides and in the form of oxygen dissolved in the solution – the melt.Chemical composition of the melt strongly influences the activity of oxygen dissolved in the melt and further on the composition of oxidic inclusions forming in the melt during the reaction with oxygen. In the Fe-C-Cr-Ni based alloys in the reaction with oxygen greatly participates also chrome, whose products are often in solid state and they are the cause of forming such defects as e.g. oxidic films.

Keywords

oxygen activity, polycomponent solution, thermodynamic equilibrium, activity coefficient

Authors

ZÁDĚRA, A.; DULAVA, M.; PERNICA, V.; KAŇA, V.

Released

25. 10. 2016

Publisher

Polish Academy of Sciences

Location

GLIWICE, POLAND

ISBN

1897-3310

Periodical

Archives of foundry engineering

Year of study

16

Number

4

State

Republic of Poland

Pages from

181

Pages to

186

Pages count

6

URL

BibTex

@article{BUT155348,
  author="Antonín {Záděra} and Martin {Dulava} and Vítězslav {Pernica} and Václav {Kaňa}",
  title="Oxygen activity in melts of Fe-C-Cr-Ni based alloys",
  journal="Archives of foundry engineering",
  year="2016",
  volume="16",
  number="4",
  pages="181--186",
  doi="10.1515/afe-2016-0106",
  issn="1897-3310",
  url="https://journals.pan.pl/Content/101950/PDF/afe-2016-0106.pdf"
}